Work

Study of an alternative route for alumina production: Integration of calcium looping to Pedersen process aiming at zero emissions and bauxite residue avoidance

Year: 2025

Type: article

Abstract: • Co-production of alumina and pig iron from bauxite via Pedersen process is modelled. • Calcium looping is studied to capture CO 2 , seizing the use of CaO of Pedersen route. • Low Al/Fe bauxites result more efficient in terms of primary energy consumption. • Iron valorization energy cost is 2.51-3.30 GJ per tonne of bauxite residue avoided. • Ca-looping integration cut energy penalties (1.10–2.79 GJ/t CO₂) by reusing purged CaO. The aluminium industry is a notable emitter of CO 2 and a significant contributor to mineral scarcity. Alumina extraction, typically conducted via the Bayer process, faces two main challenges: using fossil fuels and generating bauxite residue. A recently proposed approach, the Pedersen process, aims to address these challenges by removing the iron oxide content from the ore through an additional iron smelting step, thereby eliminating the generation of bauxite residue. This study evaluates the material and energy performance of alumina and pig iron co-production from bauxite using the principles of the Pedersen process. Different thermodynamic simulations of a Pedersen process layout were carried out using Aspen Plus software, and key parameters were validated against existing literature. Additionally, diverse CO 2 capture configurations based on calcium looping were assessed, performing an energy optimization to achieve carbon-neutral and zero-residue alumina production. Results indicate that the energy demand of the Pedersen process is notably higher than the average Bayer process for bauxites with high aluminium/iron ratios, with an estimated energy consumption of 11.92 GJ per tonne of products. However, low aluminium/iron ratios render better energy performances (10.15 GJ per tonne), showing potential feasibility in terms of energy consumption. The integration of a calcium-looping plant led to low energy penalties, thanks to the replacement of CaCO 3 in the Pedersen plant by adding purged CaO from the calcium-looping plant. The energy penalties, estimated at a minimum of 1.10-2.79 GJ per tonne of CO 2 avoided, show favourable results that could pave the way for a smarter use of resources and a decarbonized alumina production.

Source: International journal of greenhouse gas control

DOI: 10.1016/j.ijggc.2025.104453

Authors: Javier Sáez-Guinoa, Eva Llera-Sastresa, Luis M Romeo

Institutions: Universidad de Zaragoza, Instituto de Investigación en Ingeniería de Aragón

Language: English

Topic: Bauxite Residue and Utilization

Subfield: Mechanical Engineering

Field: Engineering

Domain: Physical Sciences

SDGs: Responsible consumption and production, Climate action, Affordable and clean energy, Industry, innovation and infrastructure

Open Access status: hybrid

Estimated APC paid: $4,100