Work

Synthesis of Nonconjugated TADF Polymers with Different Main Chains

Year: 2025

Type: article

Abstract: Polysiloxane and polystyrene main-chain polymers were synthesized and investigated that contain the same side chains from the moieties responsible for thermally activated delayed fluorescence (TADF) at different ratios. It was shown that the polysiloxane and polystyrene main-chain polymers can be obtained from the same TADF monomers by polymer analogues reactions of hydrosilylation with polymethylsilane PMS-60 or by free-radical polymerization, respectively. Each of the polymers obtained was characterized using gel permeation chromatography (GPC) and thermogravimetric analysis (TGA). The general conclusions of the comparative studies of the polymers are presented.

Source: INEOS OPEN

DOI: 10.32931/io2546a

Authors: R. A. Polyakov, O. V. Borshchev, S. A. Ponomarenko

Institutions: Russian Academy of Sciences, Institute of Synthetic Polymeric Materials

Language: English

Topic: Organic Light-Emitting Diodes Research

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

Open Access status: hybrid

Funder: Ministry of Science and Higher Education of the Russian Federation

Award: G4661592327