Work

Selective Adsorption Performance of a High-Capacity Mesoporous Silica Aerogel for Fluoroquinolones

Year: 2025

Type: article

Abstract: Fluoroquinolone antibiotics (FQs) are widely applied in veterinary practice and animal husbandry and frequently persist in organic waste liquids (OWLs), creating substantial environmental and health risks when untreated. A high-capacity mesoporous silica aerogel (SA-60) was produced via a cost-effective sol–gel route from water glass, followed by ambient pressure drying at 60 °C for 6 h. SA-60 exhibited pronounced selectivity, providing a maximum adsorption capacity of 630.18 mg·g−1 for enrofloxacin (ENR) in acetonitrile. Adsorption efficiency was weakly dependent on pH. Mechanistic analysis indicated combined physical and chemical interactions, with intra-particle diffusion governing the overall rate. Thermodynamic evaluation showed a spontaneous and endothermic process for ENR adsorption. Organic solvent type and water content were major determinants of adsorption efficiency. Durable performance was observed, with capacity retention above 80% after five adsorption-desorption cycles. The mesoporous architecture (surface area 249.21 m2·g−1; average pore diameter 10.81 nm) supported the high uptake. These results identify SA-60 as a sustainable adsorbent for removing hazardous FQs from OWLs, offering a simple, energy-efficient approach for the source-level control of antibiotic pollution and improved environmental management.

Source: Environments

DOI: 10.3390/environments12090300