Year: 2025
Type: article
Abstract: The increasing need for rare earth separations requires a detailed understanding of trivalent ion behavior at charged aqueous interfaces. Here, neodymium (Nd) adsorption on Langmuir monolayers of octadecylphosphonic acid (ODPA), a single‐chain phosphonic acid capable of double deprotonation, at the air/water interface, is investigated. Combining sum frequency generation (SFG) spectroscopy with X‐ray fluorescence near total reflection (XFNTR), both the interfacial water ordering and ion density are examined. Under ambient conditions, Nd ions induce enhanced deprotonation of ODPA headgroups, leading to interfacial ion densities as high as 1 Nd per 30 Å2. This adsorption behavior arises from a complex interplay between direct electrostatic interactions, ion pairing, and hydration effects, which cannot be fully captured by classical Gouy–Chapman–Stern models. These insights into trivalent ion adsorption mechanisms provide a pathway toward more effective separation processes for rare earth metals.
Source: ChemPhysChem
Authors: Srikanth Nayak, Ahmet Uysal
Institution: Argonne National Laboratory
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,550
Awards: G102163711, G107546177, G1313983767, G1664757510, NSF's ChemMatCARS: A synchrotron X-ray national facility for chemistry and materials research at the Advanced Photon Source, G2287611682, G262962599, G2959462655, G3031701862, G3075337988, G3589692066, G498139845, G513797252, G6848031779, G6918803902, G969889393, G993149817
OpenAlex ID: W4413889102