Work

Study of radiation-catalytic activity of aluminosilicate systems in the processes of hydrogen production from methane and methane-steam mixture

Year: 2025

Type: article

Abstract: The kinetics of H2 accumulation during the radiation-thermocatalytic decomposition of CH4+ 2H2O and 2CH4+H2O mixtures at T=300÷773 K (Ptot=1-12 atm) on the surface of aluminosilicate was studied. Doubling the relative concentration of methane in the reaction medium at T=773 K causes an increase in the yield of G(H2) from 1.2 to 2.3 molecule/100 eV. Based on the results obtained on the heterogeneous radiolysis of methane and the CH4+H2O mixture, the following conclusions can be drawn that the efficiency of energy transfer in the Al–Si + CH4 system is less than in the Al–Si + H2O system, and the radiation-chemical yield of molecular hydrogen at heterogeneous radiolysis of methane in the presence of amorphous aluminosilicate at PCH4≈1 atm, T=300÷773 K does not depend on temperature.

Source: Physics and Chemistry of Solid State

DOI: 10.15330/pcss.26.3.526-531

Authors: T.N. Agayev, S.Z. Melikova, I.A. Faradjzade

Institutions: Ministry of Science and Education Republic of Azerbaijan, Radiasiya Problemləri İnstitutu, Ministry of Emergency Situations of the Republic of Azerbaijan

Language: English

Topic: Catalysts for Methane Reforming

Subfield: Catalysis

Field: Chemical Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: diamond

OpenAlex ID: W4414093247

FWCI:

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