Developing High‐Rate Aqueous Zinc‐Ion Batteries with Zn‐Doped V 10 O 24 ·12H 2 O Cathode
Year: 2025
Type: article
Abstract: Aqueous zinc‐ion batteries (AZIBs) have garnered attention as a cost‐effective and safer alternative to lithium‐ion batteries (LIBs). However, developing suitable cathode materials which can reversibly host Zn2 + ions remains a challenge. Herein we explore the effect of zinc doping into hydrothermally synthesized V 10 O 24 .12H 2 O (ZVO) and demonstrate that such doping enhances electronic conductivity and structural stability, leading to improved rate capability and cycling performance of ZVO as a cathode material for AZIBs. The effect of zinc doping in the V 10 O 24 .12H 2 O as a ZIB cathode has not been previously explored. The ZVO materials had a bundled rod‐like morphology with a zinc content of 1.3% and an average oxidation state of 4.86 for the vanadium. DFT calculations further validate that Zn doping to the pristine V 10 O 24 is thermodynamically favorable, which also improves the electronic conductivity of the ZVO. As a result, the Zn//ZVO cell exhibited superior specific capacity and improved rate performance over the pristine V 10 O 24 .12H 2 O (VO) electrode, with a high specific capacity of 359 mAh/g at 0.1 A/g and sustained 121 mAh/g at 5 A/g. The Zn//ZVO cell also showed commendable cycle stability with 90 mAh/g capacity retention over 1110 cycles, which was equivalent to the starting capacity of the pristine VO cathode.
Source: Chemistry - A European Journal
Authors: Prahlada Thippeswamy, Suman Kalyan Sahoo, Hemavathi NJ, Soumen Giri, Debasis Ghosh
Institutions: Jain University, KIIT University
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: green
Funder: Central Power Research Institute
Awards: G1753919744, G6500927178
OpenAlex ID: W4414160378