Efficient Photodegradation of Congo Red and Phenol Red in Wastewater Using Nanosized Cu-Polyoxometalate: A Promising UV-Active Catalyst for Environmental Treatment
Year: 2025
Type: article
Abstract: This research focuses on the synthesis, characterization, and photocatalytic performance of Cu-based polyoxometalate (Cu-POM) as an effective catalyst for the degradation of organic dyes, specifically Congo Red (CR) and Phenol Red (PR). The main goals are to synthesize Cu-POM using a controlled self-assembly technique, characterize its optical and structural characteristics using FTIR, XRD, SEM, TGA, and UV-Vis spectroscopy, and estimate its photocatalytic activity when exposed to UV light. The outcomes confirm the successful formation of Cu-POM with well-defined nanostructures and a crystalline polyoxometalate framework. The determined optical bandgap of 3.65 eV indicates its strong UV-light responsiveness. The photocatalytic degradation experiments demonstrated high removal efficiencies of 58.1% for CR and 64.6% for PR under UV irradiation, corresponding kinetic rate constants of 0.00484 min−1 and 0.00579 min−1, respectively. The superior photocatalytic activity is attributed to the efficient charge carrier separation and high surface area of Cu-POM. These findings highlight the potential of Cu-POM as a promising heterogeneous photocatalyst for sustainable wastewater treatment and environmental remediation.
Source: Catalysts
Institution: University of Tabuk
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $2,654
Funder: University of Tabuk
OpenAlex ID: W4414529326