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Silica-Supported Vanadium-oxo-alkylidene for Self-Metathesis of Propene

Year: 2025

Type: article

Abstract: is an active catalyst for the self-metathesis of propene under flow conditions, achieving a TON of 930. This is the first report of a V-alkylidene being active for the self-metathesis of propene with activity being an order of magnitude greater than other V-based catalysts reported for the self-metathesis of olefins.

Source: Journal of the American Chemical Society

DOI: 10.1021/jacs.5c07854

Authors: Rahul Koottanil Haridasan, Shirley Hernandez, Selena Kuenzig, Gabriela Tejeda, James H. P. Collins, Konstantin V. Bukhryakov, Keith Searles

Institutions: University of Florida, Florida International University, National High Magnetic Field Laboratory

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: National Science Foundation, McKnight Foundation, Florida International University, University of Florida, National High Magnetic Field Laboratory, National Institutes of Health, National Institute of General Medical Sciences, Division of Materials Research, High Magnetic Field Laboratory, Chinese Academy of Sciences

Awards: G1019936685, G11703650, NMR console upgrade for structural biology and metabolomics, National High Magnetic Field Laboratory Renewal 2023-2027, G742574937, G8152425740, Carbon isotope exchange mediated by vanadium complexes

OpenAlex ID: W4414561330

FWCI: 0.29

Cites: 49

Cited by: 1

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