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Acidity-Tuned CeZr–Al–O Nanocatalysts for Efficient Xylose-to-Furfural Conversion under Microwave Irradiation

Year: 2025

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide The development of environmentally benign and efficient catalytic systems is essential for advancing green and sustainable biomass conversion processes. In this study, we report a series of nanostructured ternary mixed oxides based on alumina modified with 10 and 30 wt % ceria–zirconia, synthesized via a sol–gel method, for the catalytic dehydration of xylose to furfural under microwave irradiation. The catalysts were characterized by N 2 adsorption, XRD, UV–vis, and XPS techniques, revealing high surface areas, small crystallite sizes of Ce, Zr, and Al, and tunable acidity comprising the Lewis acid sites modulated by the Ce and Zr contents. The CeZr(30)–Al catalyst demonstrated a furfural yield of 65% at 170 °C in 40 min, markedly superior to that of pure Al 2 O 3, CeO 2, and ZrO 2, highlighting the benefits of oxide synergy and microwave-assisted heating. This approach not only reduces reaction time and energy consumption but also avoids the use of corrosive mineral acids, aligning with key principles of green chemistry. These findings demonstrate the potential of CeZr–Al ternary oxides as efficient, sustainable catalysts for lignocellulosic biomass valorization into platform chemicals.

Source: ACS Applied Nano Materials

DOI: 10.1021/acsanm.5c03200

Authors: Brenda Acosta, Eduardo Arenas-Sánchez, Andrey Simakov, Martin López Cisneros, Elena Smolentseva