Plasticizer-Enabled Solvent-Free Curing of Self-Healing Binder System for Energetic Materials
Year: 2025
Type: article
Abstract: Solvent processing hampers the reliability and energy density of self-healing binders for energetic materials. We report a solvent-free curing route for a Diels-Alder self-healing furanyl-terminated polybutadiene enabled by a functional external plasticizer, dibutyl phthalate (DBP), which acts not only to lower the viscosity of the binder but to disperse the high-melting bismaleimide, thereby driving crosslinked network formation. The 50 wt% DBP-plasticized film healed a pre-cut crack in 5 min at 120 °C and recovered nearly full mechanical properties after 24 h at 60 °C. Based on this binder system, a self-healing solid propellant with 80 wt% solid content was solvent-free cast into a dense and void-free grain that healed surface cracks within 5 min at 120 °C. This solvent-free approach overcomes the limitations of solvent-based processing and offers a viable fabrication route for self-healing energetic materials.
Source: Polymers
Authors: Minghao Zhang, Xudong Hou, Qifa Yao, Hanyu Chen, Zuting Wei, Yue Zhao, Zhishuai Geng, Fanzhi Yang, Min Xia, Yunjun Luo
Institution: Beijing Institute of Technology
Language: English
Subfield: Polymers and Plastics
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $3,258
Award: G695192000
OpenAlex ID: W4414622963