Work

Synthesis and photochemistry of new chiral keto[3,3]cyclophanes

Year: 2025

Type: article

Abstract: We have prepared racemates of two new chiral keto[3,3]paracyclophanes and one keto[3,3]metacyclophane by irradiation of the corresponding phenacyl benzoates tethered with a phenol moiety via conformational preorganization enabled by intramolecular charge transfer complex. Their structural properties have been analyzed by X‐ray crystallography. The photochemistry of the new cyclophanes has also been examined, in which the beta CO bond cleavage is the major reaction pathway.

Source: Bulletin of the Korean Chemical Society

DOI: 10.1002/bkcs.70068

Authors: Ho Suk Shin, Bong Ser Park

Institution: Dongguk University

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,470

OpenAlex ID: W4414626120

FWCI: 1.192

Cites: 46

Cited by: 4

Related to: