Work

Enantioselective homocoupling of allenylic alcohols through divergent cooperative catalysis

Year: 2025

Type: article

Abstract: , where a single substrate is converted into two transient intermediates of complementary polarity under the influence of two different catalysts. The selective coupling of these two polarity-matched intermediates results in the desired product. Mechanistic details are unraveled through experimental studies and density functional theory (DFT) calculations.

Source: Chemical Science

DOI: 10.1039/d5sc02831k

Authors: Aditya Chakrabarty, Ritwika Chatterjee, Santanu Mukherjee

Institution: Indian Institute of Science Bangalore

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Indian Institute of Science, Department of Science and Technology, Ministry of Science and Technology, India, Ministry of Education, India, Science and Engineering Research Board

Awards: G6438971527, G691814126