Work

Distribution Characteristics and Enrichment Mechanisms of Fluoride in Alluvial–Lacustrine Facies Clayey Sediments in the Land Subsidence Area of Cangzhou Plain, China

Year: 2025

Type: article

Abstract: Compression of clayey sediments not only causes land subsidence but also results in geogenic high fluoride groundwater. The distribution characteristics and enrichment mechanisms of fluoride in alluvial−lacustrine facies clayey sediments in the land subsidence area of Cangzhou Plain, China, were investigated using sample collection, mineralogical research, and hydrogeochemical and isotopic analysis. The results show that F− concentration of groundwater samples ranged from 0.31 to 5.54 mg/L in aquifers. The total fluoride content of clayey sediments ranged from 440 to 792 mg/kg and porewater F− concentration ranged from 0.77 to 4.18 mg/L. Clay minerals containing fine particles, such as muscovite, facilitate the enrichment of fluoride in clayey sediments, resulting in higher total fluoride levels than those in sandy sediments. The clay porewater F− predominantly originated from the dissolution of water-soluble F and the desorption of exchangeable F from sediments. The F− concentration in porewater was further influenced by ionic interactions such as cation exchange. The stable sedimentary environment and intense compression promoted the dissolution of F–bearing minerals and the desorption of adsorbed F in deep clayey sediments. The similar composition feature of δ2H−δ18O in deep groundwater and clay porewater samples suggests a significant mixing effect. These findings highlight the joint effects of hydrogeochemical and mineralogical processes on F behavior in clayey sediments.

Source: Water