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2-Fluorobenzyl ( Z )-2-(5-chloro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate dimethyl sulfoxide monosolvate

Year: 2025

Type: article

Abstract: In the title solvate, C 16 H 11 ClFN 3 OS 2 ·C 2 H 6 OS, the C=N bond adopts a Z -configuration facilitating the formation of an intramolecular N—H...O hydrogen bond to the carbonyl O atom in an S (6) loop. The dimethylsulfoxide solvent molecule accepts a strong discrete N—H...O hydrogen bond from the γ-lactam grouping. In the extended structure, C ar —H...S hydrogen bonds and quasi-Type I/II Cl...F halogen...halogen bonds are observed, while adjacent dimethyl sulfoxide molecules form S...O chalcogen-bonded chains.

Source: IUCrData

DOI: 10.1107/s2414314625008491

Authors: Aidan P. McKay, David B. Cordes, Mohd Abdul Fatah Abdul Manan

Institutions: University of St Andrews, Universiti Teknologi MARA System, Universiti Teknologi MARA

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $300

OpenAlex ID: W4414795635

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