Evaluation of Calendar Aging in Cells with Graphite: Silicon Anode Using Float Current Analysis Under the Influence of Voltage Hysteresis
Year: 2025
Type: article
Abstract: This study investigates the calendar aging of lithium-ion batteries with graphite-silicon anodes using float current analysis. While float current analysis is already a proven method for assessing aging in cells with graphite-based anodes, the presence of silicon introduces additional complexities due to its voltage hysteresis. We address this by comparing the results for the scaling factor separately for charge and discharge. The scaling factor is initially derived from charge and discharge GITT measurements on fresh cells, including an aging-induced shift among both electrode curves. This approach enables quantification of SEI growth I SEI growth , and cathode lithiation current I CL bridging measured results for float currents with capacity loss rate. As a result, the scaling factor during charge delivered the most meaningful results regarding fitted aging currents. By extending the estimation method based on the Arrhenius equation across temperatures from 5 °C to 50 °C, our model is validated against measured float currents, improving the predictive accuracy of long-term aging trends in silicon-containing anodes. Electrochemical impedance spectroscopy provided further insights into degradation mechanisms, revealing a strong correlation between cathode lithiation by salt decomposition and resistance increase at high voltages (≥4.15 V), confirmed by pulse tests at 100% SOC showing a sharp resistance increase at elevated voltages.
Language: English
Subfield: Automotive Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $1,950
OpenAlex ID: W4414867314