Year: 2025
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide This study reports the synthesis and characterization of Sb 2 (S,Se) 3 thin films for thin-film photovoltaics via a single-source close space sublimation (CSS) approach. We demonstrate power conversion efficiencies of up to 4.3% with notable improvements in open-circuit voltage ( V oc >490 mV) compared to those of Sb 2 Se 3 equivalents. Secondary ion mass spectrometry, X-ray diffraction, and cross-sectional scanning and transmission electron microscopies identified some issues in controlling film stoichiometry, particularly with sulfur loss, leading to oxide formation and elevated series resistance, reducing the fill factor in completed devices. We also identify clear discrepancies between the determined bandgap, sulfur content inferred from X-ray diffraction analysis, and sulfur content of the synthesized source material. We conclude that while CSS is a promising method for Sb 2 (S,Se) 3 film fabrication, addressing sulfur loss during deposition is crucial to achieving further improvements in device efficiency.
Institutions: University of Liverpool, Umm al-Qura University, Durham University
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W4414938564