Year: 2025
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide The C-tert- butyl substituted azacyclopropenylaluminate, [(SiN Dipp )Al-η 2 -{NC t -Bu}K] ∞ (SiN Dipp = (CH 2 SiMe 2 NDipp) 2 ) reacts with both aryl- and alkyl-substituted nitriles. In contrast to previously reported attempts to effect C–C bond formation between two dissimilar nitriles, these reactions enable the completely discriminating heterocoupling of t -BuCN to provide diazabutadienylaluminate dianions that bear two differentiated N═ C substituents.
Source: Organometallics
Institution: University of Bath
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W4415026304