Lithium salt-induced microphase separation in photopolymerized solid polymer electrolytes
Year: 2025
Type: article
Abstract: • Nanostructured SPEs fabricated by salt-induced microphase separation. • The nanostructure ultimately influences the strength and conductivity of the SPEs. • Up to a 7-fold enhancement in storage moduli compared to the neat POEGA matrix. • SPE's properties similar to crosslinked one with added benefit of recyclability. This paper reports on lithium salt-induced microphase separation of linear and star block copolymers (BCPs) dispersed in monomer to produce solid polymer electrolytes (SPEs). The proposed one-step photopolymerization methodology uses pre-synthesized BCPs of Poly (styrene- co -benzyl methacrylate)- b -Poly [oligo(ethylene glycol) methyl ether acrylate] (P(S- co -BzMA)- b -POEGA) solubilized with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in oligo (ethylene glycol) methyl ether acrylate (OEGA). The resulting kinetically arrested glassy nano-domains of P(S- co -BzMA) are later fixed during the POEGA homopolymer matrix photopolymerization. A variety of morphologies can be produced by adjusting lithium salt content and BCP architectures, i.e. , linear or star-like. Embedding the BCP nanostructures in the POEGA matrix acted as physical crosslinking that enhances the mechanical strength by a factor of seven, compared to un-crosslinked POEGA, without sacrificing on ionic conductivity. Remarkably, these innovative materials not only match the mechanical properties and conductivity of traditional cross-linked POEGA-based SPEs, but also open a valuable way towards recyclability.
Source: Applied Materials Today
Authors: Kingsley Ikenna Aniagbaoso, Monika Król, Janne Ruokolainen, Antoine Bousquet, Maud Save, Laurent Rubatat
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,400
OpenAlex ID: W4415198265