Work

Strategy for Obtaining Consensus Solubility Values with Measurement Uncertainties at Given Temperatures from Published Data

Year: 2025

Type: article

Abstract: A strategy for determining consensus solubilities with measurement uncertainties at common temperatures from data reported at varying temperatures is presented. The approach involves fitting the individual data sets to an appropriate equation of solubility (or log solubility) as a function of temperature. This allows estimation of the standard uncertainty of each data point and, if required, interpolated values of the solubility, with uncertainties, at the temperatures of interest. Between-laboratory uncertainty is assessed by the DerSimonian–Laird procedure. The strategy is applicable to any measured quantity where its variation with experimental variables can be represented by a robust equation.

Source: Journal of Solution Chemistry

DOI: 10.1007/s10953-025-01519-3

Authors: W. Earle Waghorne, D. Brynn Hibbert

Institutions: University College Dublin, UNSW Sydney

Language: English

Topic: Crystallization and Solubility Studies

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,490

Funder: University of New South Wales