Work

Pilot Study on Fingerprinting the Isotopic Signatures of Fossiliferous Limestones as a Tool for Forensic Investigation of Fossil Trafficking (Cretaceous Crato Formation, Brazil)

Year: 2025

Type: article

Abstract: Unauthorized fossil trafficking violates national legislation and deprives cultural and natural heritage. This study proposes a pilot method to fingerprint the origin of fossils by characterizing the carbon and oxygen stable isotope signatures of fossil-bearing limestones to provide a non-destructive quantitative tool against illegal fossil trade. This promising approach has been applied to the Crato Formation (NE Brazil), which is a renowned Lower Cretaceous fossiliferous lacustrine limestone. This study aims at establishing the range of isotopic oxygen (δ18O) and carbon (δ13C) values of the Crato Formation’s laminated calci-mudstone by compiling isotopic data from previous studies, conducting new analyses, and comparing with other fossiliferous lacustrine limestones from Brazil (Cretaceous Codó Formation) and the USA (Eocene Green River Formation). This preliminary evaluation determined a distinctive isotopic signature of the Crato Formation fossil-bearing “sete cortes” (“seven cuts”) ethnostratum, with VPDB δ18O and δ13C arithmetic means of −5.94‰ and +0.90‰, standard deviations 0.76‰ and 0.61‰, medians of −5.89‰ and +0.73‰, and interquartile ranges of 1.47‰ and 1.24‰, respectively. This pilot investigation establishes a methodological groundwork for the development of a global database integrating lithofacies and geochemical parameters of fossil-bearing limestones to expedite the identification and restitution of illegally extracted paleontological heritage.

Source: Geosciences

DOI: 10.3390/geosciences15100403

Authors: Marcos Antônio Pimentel de Sousa, Daniel Rodrigues do Nascimento Junior, Anelize Manuela Bahniuk, Giovanna Della Porta

Institutions: Federal Police of Brazil, Universidade Federal do Ceará, Universidade Federal do Paraná, University of Milan

Language: English

Topic: Paleontology and Stratigraphy of Fossils

Subfield: Paleontology

Field: Earth and Planetary Sciences

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $2,172