Work

On the Synthesis, Structure and Reactivity of Mes DPM Triel Dihydrides

Year: 2025

Type: article

Abstract: Herein, the simple synthesis of triel dihydride complexes with the sterically demanding 1,5,9‐trimesityldipyrromethene ( Mes DPM) ligand is reported. With these compounds, reactivity studies are carried out, opening access to new classes of Mes DPM triels. All compounds are fully characterized by standard analytic methods such as NMR, IR, and UV/vis spectroscopy as well as mass spectrometry. In addition, the molecular structures in solid state are determined by single‐crystal X‐ray diffraction analysis. In some instances, green fluorescence can also be observed upon solar irradiation, which prompted further investigations of the photoluminescence behavior.

Source: European Journal of Inorganic Chemistry

DOI: 10.1002/ejic.202500403

Authors: Lukas Erlemeier, Ajna Tomori, Manuel Burkert, Marius J. Müller, Sangam Chatterjee, Carsten von Hänisch

Institutions: Philipps University of Marburg, Justus-Liebig-Universität Gießen

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,050

Funder: Deutsche Forschungsgemeinschaft