Work

The role of phosphorus in the solid electrolyte interphase of argyrodite solid electrolytes

Year: 2025

Type: article

Abstract: The solid electrolyte interphase that forms on Li 6 PS 5 Cl argyrodite solid electrolytes has been reported to continually grow through a diffusion-controlled process, yet this process is not fully understood. Here, we use a combination of electrochemical and X-ray photoelectron spectroscopy techniques to elucidate the role of phosphorus in this growth mechanism. We uncover how Li 6 PS 5 Cl can decompose at potentials well above the full reduction to Li 3 P, forming partially lithiated phosphorus species, Li x P. We provide evidence of a gradient of Li x P species throughout the solid electrolyte interphase and propose a growth mechanism in which the rate-determining step is the diffusion of lithium through Li x P. We predict continuous solid electrolyte interphase growth as long as metallic lithium is present and a Li x P percolation pathway exists, highlighting the importance of understanding and engineering solid electrolyte interphase composition and nanostructure in solid-state batteries. We believe that this growth mechanism would apply to any solid electrolyte interphase that can contain partially lithiated phosphorus, or potentially any lithium alloy.

Source: Nature Communications

DOI: 10.1038/s41467-025-64357-3