Work

Dual‐Functional Additive Regulating Zn 2+ Solvation Structure and (002) Plane‐Oriented Deposition for Dendrite‐Free Zn Anodes

Year: 2025

Type: article

Abstract: Aqueous zinc‐ion batteries (AZIBs) are expected to be a next‐generation electrochemical energy storage system due to their high safety and low cost. However, dendrite growth and side reactions of Zn anodes have significantly hindered the advancement of AZIBs. The present study proposes the use of sulfosalicylic acid (SSA) as a bifunctional additive. First, the solvated structure of Zn 2+ is reconstructed by SSA through the synergistic effects of its hydroxyl (−OH), carboxyl (−COOH), and sulfonic (−SO 3 H) functional groups, effectively inhibiting hydrogen evolution reaction (HER) and other side reactions. Second, the SSA promotes the preferential deposition of Zn 2+ on the (002) crystal plane through selective adsorption, thereby suppressing the longitudinal growth of Zn and ultimately achieving a dendrite‐free Zn anode. Consequently, the Zn anode in the SSA/ZSO electrolyte exhibits a stable cycling capacity of over 2850 h at 1 mA cm −2 , accompanied by a coulombic efficiency of 99.7%. Furthermore, the assembled Zn|CNT/MnO 2 battery demonstrates a capacity retention of 97.7% after 600 cycles, while the Zn||VO 2 battery retains 78% of its capacity after 1100 stable cycles. This further validates the broad applicability and exceptional performance of SSA in different cathode systems. This study offers new insights into the electrolyte design for AZIBs.

Source: Advanced Functional Materials

DOI: 10.1002/adfm.202518704