Work

Erbium Orthoniobate-Tantalates: Structural, Luminescent and Mechanical Properties of ErNbxTa1−xO4 Ceramics and Bactericidal Properties of ErNbO4 Powder

Year: 2025

Type: article

Abstract: Fine powders of erbium niobate-tantalates ErNbxTa1−xO4 (x = 0; 0.1; 0.3; 0.5; 0.7; 0.9; 1) have been synthesized by the liquid-phase method in this study. Ceramic samples have been prepared using conventional sintering from these powders. Rietveld refinement of XRD patterns of polycrystals determined the phase composition and clarified the parameters of the phase structure of ErNbxTa1−xO4 solid solutions depending on the Nb/Ta ratio. The morphological features of the microstructure of erbium niobate-tantalate ceramics have been studied. Their mechanical properties, strength characteristics (Young’s modulus, microhardness) and critical stress intensity factor of the first kind KIC have been estimated. The photoluminescent properties of ceramic solid solutions of erbium niobate-tantalates depending on the composition have been studied. Dark and photoinduced toxicity of finely dispersed ErNbO4 powders have been studied in relation to Gram-positive, Gram-negative and spore-forming microorganisms. The best indicators of antibacterial activity of ErNbO4 have been demonstrated in relation to Gram-positive cells of Micrococcus sp. The discovered properties open up the possibility of not only traditional use as functional materials, but also the use of these materials for disinfection of surfaces, water and biological tissues.

Source: Ceramics

DOI: 10.3390/ceramics8040130