Cover Feature: A Structurally Unique {Fe(NO) 2 } 10 ‐{Fe(NO) 2 } 9 Dinuclear Dinitrosyl Iron Complex Bridged by a μ‐ƞ 2 ‐FBF 3 − Ligand and Stabilized by N‐Heterocyclic Carbenes
Year: 2025
Type: article
Abstract: An angelic figure holds a dinuclear dinitrosyl iron complex (DNIC) formed from {Fe(NO)₂}10 and {Fe(NO)₂}9 mononuclear precursors, epitomizing the elegance and precision of this unique molecule. With its rare μ-η2-FBF₃ bridge and stabilization by N-heterocyclic carbenes, like an angel's gentle magic touch, the complex delicately holds and balances redox and structural forces in coordination chemistry, harmonizing electronic and steric finesse. More information can be found in the Research Article by C.-H. Hsieh and co-workers (DOI: 10.1002/chem.202502404).
Source: Chemistry - A European Journal
DOI: 10.1002/chem.70299
Authors: Yung‐Chuan Chuang, Ching‐Wen Lin, Yi‐Hung Wu, Yu‐Hsien Chang, Chung‐Hung Hsieh
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W4415470713
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