Work

Transforming Renewable Carbohydrate-Based Polymers into Oxygen and Moisture Barriers at Elevated Humidity

Year: 2025

Type: article

Abstract: High Resolution Image Download MS PowerPoint Slide The widespread usage of nonrenewable plastics in packaging has resulted in a significant environmental burden, and the industry is working to adopt renewable biopolymers in place of traditional plastics. However, renewable biopolymers often lack sufficient gas-barrier properties at an elevated relative humidity (RH). Here, we demonstrate that the introduction of citric acid (CA) cross-linkers to cellulose nanocrystal (CNC)/chitosan (Ch) blends significantly reduces the oxygen permeability (OP) and water vapor transmission rate (WVTR) at high RH. Specifically, in CNC/Ch binary systems (without CA), as in many plastic packaging materials, the OP value increases dramatically (approximately 45×) when increasing RH from 50 to 80%. In contrast, CNC/Ch/CA ternaries feature low OP of 0.59 cm 3 μm·m –2 day –1 kPa –1 at 23 °C/80% RH, similar to the OP at 50% RH. This ternary system, with additional heat treatment, also exhibits an extremely low thickness-normalized WVTR of 0.005 g·mm·m –2 day –1 at 23 °C and 50% RH. The WVTR rises to 14 g·mm·m –2 day –1 at 38 °C/80% RH, still approximately 10× lower than that of neat CNCs.

Source: ACS Applied Polymer Materials

DOI: 10.1021/acsapm.5c02909