Emergence of long-range non-equilibrium correlations in free liquid diffusion
Year: 2025
Type: article
Abstract: It is experimentally well-established that non-equilibrium long-range correlations of concentration fluctuations appear in free diffusion of a solute in a solvent, but it remains unknown how such correlations are established dynamically. We address this problem in a model of Donev, Fai, and Vanden-Eijnden (DFV), obtained from the high-Schmidt limit of the Landau-Lifshitz fluctuating hydrodynamic equations for a binary mixture. We consider an initial planar interface of the mean concentration field in an infinite space domain, idealizing prior experiments. Using methods borrowed from turbulence theory, we show both analytically and numerically that a quasi-steady regime with self-similar time decay of concentration correlations appears at long time. In addition to the expected "giant concentration fluctuations" with correlations ∝r for r ≲ L(t) = (Dt)1/2, with diffusivity D, a new regime with spatial decay ∝1/r appears for r ≳ L(t). The quasi-steady regime arises from an initial stage of transient growth ∝t, confirming the prediction of DFV for r ≳ L(t) and discovering an analogous result for r ≲ L(t). Our results give new insight into the emergence of non-equilibrium long-range correlations and provide novel predictions that may be investigated experimentally.
Source: The Journal of Chemical Physics
DOI: 10.1063/5.0292952
Institutions: Sapienza University of Rome, Johns Hopkins University
Language: English
Subfield: Computational Mechanics
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $3,500
OpenAlex ID: W4415583262