Work

Color-Tunable Intrinsically Black Polyimides: A Facile Strategy via In Situ Oxidation Color Control

Year: 2025

Type: article

Abstract: Black polyimide (BPI) has shown important value in the field of optical engineering due to its excellent light shielding, high temperature stability, and mechanical strength. However, carbon materials or organic dye-doped BPI suffer from poor insulation, low mechanical strength, and poor thermal stability. Intrinsic BPI has gradually become a hot topic of research at this stage. Polyimides containing dianiline structure have unique reducing activity, and the visible light absorption range can be expanded by adding an oxidant in situ to achieve BPI preparation. In this work, a polymerizable dianiline derivative- 2,4-diaminodiphenylamine (NPDA) has been developed. The resulting diamine monomers were then polymerized with a dianhydride monomer via a conventional two-step method to prepare soluble polyimide. The diphenylamine-containing group PI was characterized by 1H NMR, FTIR and UV absorption spectroscopy. It was found that by changing the oxidant ratio, a yellow, red and even black controllable polyimide film could be obtained. When fully oxidized, the BPI cutoff wavelength red shifts to 591 nm, light transmittance reaches as low as 5.9% (full visible light 300-700 nm mean), and BPI can maintain the electrical insulation and heat resistance of polyimide. This method of oxidizing soluble polyimide in situ has advantages such as economy, universality, process consistency, ease of access and superior performance.

Source: Polymers

DOI: 10.3390/polym17212876