Experimental and theoretical study on the thermal stability and pyrolysis mechanism of HCFO-1233 yd.(Z)
Year: 2025
Type: article
Abstract: The thermal stability and decomposition mechanism of (Z)-1,1,1-trifluoro-3-chloroprop-2-ene (HCFO-1233 yd.(Z)) were systematically investigated through combined theoretical and experimental approaches. The thermal decomposition of HCFO-1233 yd.(Z) proceeds predominantly through homolytic bond cleavage, radical abstraction, intermediate decomposition, and radical recombination, with oxidative decomposition representing the thermodynamically favored pathway. The primary decomposition products consist of two structural isomers with the molecular formula C3F3H2OCl.
Source: Results in Chemistry
Authors: Zhang Dongxin, Ouyang Hongsheng, Sun Xiang, Xu zheng, Fu lichen, Yan hongfei, Guo zhikai, Jiang Jintian
Language: English
Topic: Thermal and Kinetic Analysis
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,870
Award: G2901035237
OpenAlex ID: W4415641415