Year: 2025
Type: article
Abstract: -CPBA oxidation. The methodology offers versatile approaches that can be adapted based on the solubility of reaction intermediates, enabling either one-pot or two-stage synthesis pathways. Four distinct synthetic methods were established, accommodating a wide range of arenes and diiodoarenes, including sterically hindered and electron-deficient substrates. The resulting bis(iodonium) salts were isolated in good to excellent yields (up to 99%). X-ray crystallographic analysis of these compounds revealed intriguing supramolecular organization in the solid state, with the formation of 1D chains through halogen bonding interactions. These self-assembled architectures demonstrate the potential of bis(iodonium) cations as valuable building blocks for applications in crystal engineering.
Source: The Journal of Organic Chemistry
Institutions: Tomsk Polytechnic University, Siberian Branch of the Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, St Petersburg University, Russian Academy of Sciences, N.D. Zelinsky Institute of Organic Chemistry, Politecnico di Milano, Novosibirsk Institute of Organic Chemistry
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
Award: G5842753253
OpenAlex ID: W4415685132