Synthesis of MOF-Derived Mono-, Bi- and Trimetallic Fe, Zn and Cu Oxides for Microwave-Assisted Benzyl Alcohol Oxidation
Year: 2025
Type: article
Abstract: The increasing demand for sustainable chemical processes has fostered the development of advanced catalytic systems for biomass valorization. In this work, a series of mono-, bi-, and trimetallic oxides (FeO, FeCuO, FeZnO, and FeCuZnO) were successfully synthesized using MIL-101-based MOFs as sacrificial templates. The obtained materials were thoroughly characterized by N2 adsorption–desorption, XRD, FTIR, and TEM/STEM-EDX to investigate their structural, morphological, and textural properties. Their catalytic performance was evaluated in the selective oxidation of benzyl alcohol, a lignin-derived platform molecule, into benzaldehyde under microwave irradiation as a sustainable heating strategy. The results demonstrate that MOF-derived oxides exhibit superior activity compared to their parent MOFs, highlighting the beneficial effect of thermal treatment on the exposure of active sites. Among the catalysts, heterometallic oxides showed enhanced performance due to synergistic effects between metals. In particular, FeZnO reached a maximum yield of 62.1% towards benzaldehyde at 150 °C and 30 min, outperforming the monometallic oxide. Recycling tests revealed that FeZnO retained higher overall performance than FeCuO, which suffered from progressive copper leaching. These findings confirm the potential of MOF-derived multimetallic oxides as efficient and reusable heterogeneous catalysts for selective biomass-derived alcohol oxidation. The combination of microwave-assisted processes and the tuneable nature of MOF-derived oxides provides a promising pathway for designing sustainable catalytic systems with industrial relevance.
Source: Catalysts
Institution: University of Córdoba
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $2,654
Award: G3690828678
OpenAlex ID: W4415817104