Work

High-Performance Fluoride Removal from Water Using MgO Nanoparticles Synthesized via DMF-NH4+ Co-Precipitation

Year: 2025

Type: article

Abstract: Fluoride contamination in groundwater is a pressing environmental and public health issue, with chronic exposure linked to skeletal and dental fluorosis. Here, we report the synthesis of magnesium oxide nanoparticles via a controlled co-precipitation method employing dimethylformamide (DMF) as solvent and either ammonium hydroxide (MgO-1) or ammonium carbonate (MgO-2) as precipitating agents. The resulting materials were comprehensively characterized using thermogravimetric analysis (TGA/DSC), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS). Additionally, BET surface area and porosity analyses revealed mesoporous structures, with MgO-1 showing a slightly higher surface area (14.12 m2 g−1) than MgO-2 (13.87 m2 g−1). Both MgO-1 and MgO-2 exhibited high crystallinity, nanoscale particle sizes (81.6 nm and 128.1 nm, respectively), and distinct morphological features. Batch adsorption studies revealed maximum fluoride uptake capacities of 117.6 mg/g (MgO-1) and 94.5 mg/g (MgO-2) at neutral pH, with MgO-1 exhibiting superior performance due to its smaller particle size and higher specific surface area. Fluoride removal remained above 98% between pH 3–9, confirming stability across a wide pH range, with a minor decline at pH 11 due to OH− competition. Adsorption equilibrium data were best described by the Temkin isotherm model, suggesting heterogeneous surface interactions and an exothermic process, while kinetic analyses indicated pseudo-second-order behavior for MgO-1 and pseudo-first-order for MgO-2. Both materials maintained high fluoride selectivity in the presence of competing anions and successfully reduced fluoride in tap water from 2.11 mg/L to below the WHO limits without altering water hardness. These findings underscore the potential of engineered MgO nanomaterials as efficient, selective, and sustainable adsorbents for water defluoridation, offering a promising pathway toward scalable remediation technologies in fluoride-affected regions.

Source: Inorganics

DOI: 10.3390/inorganics13110370