Work

The effect of the large cation matrix and delocalization of electronic density on the switchable behaviour of heterotrimetallic cyanido-bridged Fe x Mn 9− x W 6 clusters

Year: 2025

Type: article

Abstract: A Mn( ii )-cation-based large matrix stabilizes the HT phase and shapes the phase transitions and spin-state equilibria in a trimetallic {FeIIxMnII9−x[W V (CN) 8 ] 6 (MeOH) 24 }· n MeOH cluster series.

Source: Inorganic Chemistry Frontiers

DOI: 10.1039/d5qi01515d

Authors: Jedrzej Kobylarczyk, Marcin Kozieł, Katarzyna Dziedzic-Kocurek, Jan M. Michalik, Dawid Pinkowicz, Magdalena Fitta, Barbara Sieklucka, Robert Podgajny

Institutions: Jagiellonian University, Institute of Nuclear Physics, Polish Academy of Sciences, AGH University of Krakow

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funders: European Commission, Narodowe Centrum Nauki, Ministerstwo Edukacji i Nauki, European Regional Development Fund

Awards: G1130753063, G3936740076, G410470735, G649876508, G990639777

OpenAlex ID: W4415914558

FWCI: 0.163

Cites: 102

Cited by: 1

Related to: