Work

Phosphorus chirality assignment and solution dynamics of lanthanide( iii ) complexes of a monomethylphosphinate analogue of H 4 dota: a multinuclear NMR and DFT study

Year: 2025

Type: article

Abstract: Orientation of the substituents of the coordinated phosphinate group was experimentally determined for the first time and exchange between its coordinated/non-coordinated oxygen atoms (“phosphinate rotation”) was experimentally/computationally confirmed.

Source: Inorganic Chemistry Frontiers

DOI: 10.1039/d5qi01885d

Authors: Adam Svítok, Carlos Platas-Iglesias, Jan Kotek, Petr Hermann

Institutions: Charles University, Universidade da Coruña

Language: English

Topic: Lanthanide and Transition Metal Complexes

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funders: Univerzita Karlova v Praze, Ministerstvo Školství, Mládeže a Tělovýchovy, Grantová Agentura České Republiky

Awards: G1761812275, G5960638817, G8227998441, Complexes of fluorinated ligands with paramagnetic metal ions for 19F MRI and bimodal 1H/19F contrast agents