Work

A facile route to ‘naked’ Ag + ions enabling the coordination of the weak Lewis base Ni(CO) 4

Year: 2025

Type: article

Abstract: We report an easy method to generate highly electrophilic Ag + ions in combination with a very weakly-coordinating counteranion. This allowed the first structural characterization of a metal complex featuring Ni(CO) 4 as a Lewis base.

Source: Chemical Science

DOI: 10.1039/d5sc05589j

Authors: Willi R. Berg, Amina L. Moshtaha, Robin Sievers, Marc Reimann, Tim-Niclas Streit, Susanne M. Rupf, Martin Kaupp, Moritz Malischewski

Institutions: Freie Universität Berlin, Universität Innsbruck, Technische Universität Berlin

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Fonds der Chemischen Industrie, Deutsche Forschungsgemeinschaft, Austrian Science Fund, Freie Universität Berlin

Awards: G3645873082, G4495373907, SFB 1349: FluorSpezifische Wechselwirkungen: Grundlagen und Anwendungen, G9000146505

OpenAlex ID: W4415999283

FWCI: 0.596

Cites: 59

Cited by: 2

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