Work

Elementary Steps of Energy Conversion in Strongly Correlated Systems: Beyond Single Quasiparticles and Rigid Bands

Year: 2026

Type: article

Abstract: Energy conversion in materials can be considered as a sequence of elementary steps initiated by a primary excitation. While these steps are quite well understood in classical semiconductors in terms of quasiparticle excitations and interactions, their understanding in strongly correlated materials is still elusive. Here, we review the progress which has been achieved over recent years by studies of manganite perovskite oxides as a model system for materials with strong correlations. They show a subtle interplay of different types of correlations, that is, electron–phonon, electron–electron, and spin–spin, resulting in rich physical phenomena due to competition between different ground states accompanied by temperature‐ and field‐induced phase transitions. They strongly impact various types of energy conversion and transport processes including friction at surfaces, thermal transport, time‐, energy‐, power‐dependent optical excitations as well as photovoltaic energy conversion. The underlying microscopic processes can be broken down to the behavior of the low‐energy thermal and high‐energy optical excitations, their interactions, transport and conversion which are theoretically analyzed by using models of interacting and tunable quasiparticles: Their nature and interactions can change during excitation, transport and phase transitions, thus modifying electronic structure. At sufficiently high stimulation, quasiparticle excitations can even induce or actuate phase transitions. As a result, we obtained a comprehensive understanding of energy conversion steps going far beyond single quasiparticle pictures and rigid band approximations well known for conventional semiconductors.

Source: Energy & environment materials

DOI: 10.1002/eem2.70366