Work

Structures of a 2-Pyrenolato-Coordinated Gallium Porphyrin with an Additional 2-Pyrenol Bound via Hydrogen Bonding

Year: 2025

Type: article

Abstract: The structure of a 2-pyrenolato–coordinated gallium porphyrin complex incorporating an additional hydrogen-bonded 2-pyrenol molecule has been determined [monoclinic, a = 18.60720(10) Å, b = 15.74080(10) Å, c = 28.3753(2) Å, β = 106.9530(10)°, space group P 2₁/ c ]. The additional 2-pyrenol molecule forms a hydrogen bond with the oxygen atom of the coordinated 2-pyrenol. The gallium ion (Ga 3 ⁺) is five-coordinate, adopting a square-pyramidal geometry with four nitrogen atoms from the porphyrin ligand and one oxygen atom from the 2-pyrenolato ligand. The Ga–O bond distance is 1.8799(15) Å, which deviates from previously reported values for gallium porphyrins bearing oxygen-containing axial ligands. The introduction of 2-pyrenol imparts properties characteristic of pyrene, namely CH–π and π–π interactions. Graphical Abstract This paper describes a crystallographic study of a gallium porphyrin complex coordinated with 2-pyrenolato and incorporating an additional hydrogen-bonded 2-pyrenol molecule.

Source: Journal of Chemical Crystallography

DOI: 10.1007/s10870-025-01071-4

Authors: Shafikul Islam, Masashi Hasegawa, Ken-ichi Sugiura

Institutions: Jahangirnagar University, Tokyo Metropolitan University, Kitasato University

Language: English

Topic: Porphyrin and Phthalocyanine Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $3,190

Funders: Tokyo Metropolitan University, Core Research for Evolutional Science and Technology