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Carrier-assisted recombination in anatase TiO2

Year: 2025
Type: article
Abstract: Differential optical transmission experiments performed on TiO2 layers reveal a carrier population decay that follows a power-law over several orders of magnitude in both time and signal amplitude, across a temperature range from 10 K up to room temperature. The exponent of the power-law is fractional, increasing linearly at low temperatures before following an activation law above 160 K. We propose a mechanism based on collision-assisted recombination, where self-trapped excitons are first delocalized and then partially ionized into free polarons as the temperature increases, giving rise to the acceleration of the population decay.
Language: English
Field: Energy
Open Access status: hybrid
Estimated APC paid: $3,500
OpenAlex ID: W4416169707
FWCI:
Cites: 31
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