Work

Confinement-induced flow resistance in polystyrene thin films: A semi-empirical framework for nanoimprint lithography

Year: 2025

Type: article

Abstract: This study investigates the deformation behavior of spin-coated polystyrene (PS) thin films under nanoscale confinement during thermal nanoimprint lithography (T-NIL). As film thickness approaches the radius of gyration ( ), polymer flow is significantly suppressed, and deformation resistance increases even under moderate imprinting pressures. To quantify this behavior, a semi-empirical model is developed that incorporates three physically meaningful parameters: bulk-limit deformability, critical cavity size linked to coil dimensions and entanglement thresholds, and confinement-induced resistance scaling. Experimental results reveal a sharp rise in the confinement-induced resistance scaling parameter below ∼7 , indicating strong confinement effects associated with reduced segmental mobility and disrupted entanglement networks. Complementing this framework, an apparent viscosity model is constructed based on modified Poiseuille flow. The apparent viscosity exhibits an inverse power-law dependence on film thickness, closely mirroring the classical scaling law of viscosity with molecular weight ( ) in entangled polymer melts. Together, these models provide predictive insight into deformation resistance in confined polymer systems and offer quantitative guidelines for NIL process optimization. Beyond NIL, the findings contribute to a broader understanding of rheological behavior in polymer thin films under geometric confinement. • Understanding polymer flow under nanoscale confinement is challenging. • Nanoimprint lithography (NIL) offers a platform to probe confinement effects on polymer deformation. • A semi-empirical model links film thickness, cavity size, and flow resistance. • Deformation drops sharply below seven times the radius of gyration, while apparent viscosity increases. • Power-law scaling reveals confinement mimics higher molecular weight behavior.

Source: Polymer Testing

DOI: 10.1016/j.polymertesting.2025.109039

Authors: Sung Nam Moon, Jin Woo Song, Sang Yup Kim, Woo Il Lee

Institutions: Seoul National University, LG Chem (South Korea), Sogang University

Language: English

Topic: Rheology and Fluid Dynamics Studies

Subfield: Fluid Flow and Transfer Processes

Field: Chemical Engineering

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $3,370

Funders: Korea University, National Research Foundation of Korea