Work

Nitric Acid Leaching for Magnesium Extraction from Asbestos Ore Waste: From DoE to Predictive Modeling and Cost-Efficient Optimization

Year: 2025

Type: article

Abstract: Kazakhstan’s asbestos industry produces over 3 million tons of waste annually. The primary component of asbestos ore waste (AOW) is magnesium rich minerals. In this study, the extraction of magnesium from AOW with nitric acid (HNO3) was for the first time systematically studied. A series of experiments were conducted to optimize acid concentration (300–600 g/L), leaching temperature (55–95 °C), leaching time (60–180 min), solid-to-liquid ratio (1:3–1:7), and particle size, with the overall goal of maximizing magnesium extraction and cost efficiency. Our results provide dependence of magnesium extraction in the order of acid concentration > temperature > time > solid-to-liquid ratio, while particle size was found to be negligible. The cost-efficiency optimization demonstrated the positive impact of the relatively low acid concentrations (< 450 g/L) and temperatures between 65 and 85 °C, while the Protodyakonov model validated a linear dependence of the extraction rate on temperature and acid concentration. Our model demonstrates that extraction efficiencies of up to 90% can be achieved while reducing reagent use and lowering the overall cost of magnesium production. Leaching of magnesium by HNO3 also opens a pathway to a closed-cycle process, due to the formation of magnesium nitrate. The thermal decomposition of Mg(NO3)2 provides valuable products such as MgO and NO2 reused in HNO3 regeneration for subsequent cycles. The proposed model predicts magnesium extraction from asbestos ore depending on leaching parameters with reasonable accuracy.

Source: Molecules

DOI: 10.3390/molecules30224396