Work

Investigation of ZnMgO/µc-Si thin-film solar cell using two-dimensional numerical simulation

Year: 2025

Type: article

Abstract: The development of efficient microcrystalline silicon ( µ c-Si) thin-film solar cells offers a promising route to reduce photovoltaic costs. This work presents, for the first time, a comprehensive numerical model to optimize ZnMgO/µc-Si-based solar cells by analyzing its performance metrics. The model incorporates horizontal and vertical grain boundaries (GBs) in the absorber with Gaussian-distributed donor- and acceptor-like trap states. Key parameters studied are Mg concentration, thickness, and doping in the ZnMgO emitter, as well as GB-induced recombination in the µ c-Si absorber. Results show that increasing Mg concentration up to 20% significantly enhances performance, while higher concentrations yield negligible improvement. GB recombination critically affects performance: smaller grain size, which increases GB density, causes exponential degradation, and GB trap densities above 10 11 cm − 2 lead to a sharp decline in metrics. The ZnMgO emitter exhibits optimal performance at ~ 100 nm thickness and ~ 5 × 10 16 cm − 3 doping. A maximum efficiency of ~ 14.3% is achieved with 20% Mg, 100 nm thickness, 5 × 10 16 cm − 3 doping in ZnMgO, and an absorber containing 10 GBs with trap density of 10 11 cm − 2 . The model is validated against previously reported results.

Source: Scientific Reports

DOI: 10.1038/s41598-025-23415-y

Authors: Muzaffar Imam, Md. Akram Ahmad, Paramjit Kaur, Mukul Kumar Das, Syed Sadique Anwer Askari

Institutions: Presidency University, Galgotias University, Sant Longowal Institute of Engineering and Technology, Indian Institute of Technology Dhanbad, Manipal University Jaipur

Language: English

Topic: Silicon and Solar Cell Technologies

Subfield: Electrical and Electronic Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Affordable and clean energy

Open Access status: gold

Estimated APC paid: $2,690