Work

Source and Precipitation Process of Gold in the Linglong Gold Deposit, Jiaodong Peninsula: Constraints from Trace Elements of Pyrite and S-Pb Isotopes

Year: 2025

Type: article

Abstract: Jiaodong Gold Province is a globally rare giant gold cluster, with ongoing debates regarding its metallogenic material sources and mineralization mechanisms. This study focuses on the Linglong quartz-vein-type gold deposit within the Zhaoping Fault Zone, conducting in situ trace element and S-Pb isotope analyses of pyrite from different mineralization stages. The trace element characteristics were investigated to explore the sources of metallogenic materials, the evolution of ore-forming fluids, and the mechanisms of gold precipitation. The main findings are as follows: (1) In the Linglong gold deposit, gold primarily enters the pyrite lattice as a solid solution (Au+) through Au-As coupling. From the Py1 to Py3 stages, Co and Ni contents significantly decrease, while Cu, As, Au, and polymetallic element contents continuously increase. Additionally, Cu mainly replaces Fe2+ in the form of Cu2+, whereas Pb predominantly exists as micro inclusions of galena. (2) The S isotope (Py1: δ34S = +7.60‰–+8.25‰, Py2: δ34S = +6.15‰–+8.15‰, Py3: δ34S = +6.90‰–+9.10‰) and Pb isotope (206Pb/204Pb = 16.95–17.715, 207Pb/204Pb = 15.472–15.557, 208Pb/204Pb = 37.858–38.394) systems collectively constrain the ore-forming materials such that they are dominated by metasomatized enriched lithospheric mantle, with simultaneous mixing of crustal materials. (3) The ore-forming fluid underwent a continuous evolution process characterized by persistently decreasing temperatures and a transition from mantle-dominated to crust–mantle mixed sources. The Py1 stage was predominantly composed of mantle-derived magmatic fluids uncontaminated by crustal materials, representing a high-temperature, closed environment. In the Py2 stage, the fluid system transitioned to an open system with the incorporation of crustal materials. Through coupled substitution of “As3+ + Au+ → Fe2+” and dissolution–reprecipitation processes, gold was initially activated and enriched. During the Py3 stage, pyrite underwent dissolution–reprecipitation under tectonic stress and fluid activity, promoting extraordinary element enrichment and serving as the primary mechanism for gold precipitation. Concurrently, bismuth–tellurium melt interactions further facilitated the precipitation of gold minerals.

Source: Minerals

DOI: 10.3390/min15111220