Work

Investigation of staging techniques for hydrocarbon-assisted ammonia flames in a novel dual-stage combustor

Year: 2025

Type: article

Abstract: Ammonia presents itself as a high-hydrogen dense and carbon-free alternative for industrial heating, power generation, and transportation. Nevertheless, the challenges of its low flame speed and elevated NO x (nitrogen oxides) emissions pose significant challenges in combustor applications. This study investigates a novel two-stage burner employing a radial injection staging technique and explores various NO x reduction strategies for hydrocarbon-assisted ammonia flames. These strategies include premixing, fuel staging, balanced fuel staging, air staging, and sequential premixing. The focus is on LPG (liquid petroleum gas)-stabilized ammonia flames. The experiments are conducted at a constant thermal input of 20 kW (10 kW LPG + 10 kW NH 3 ), with global equivalence ratios ranging from 0.7 to 1.4. This approach aims to provide valuable insights into the effectiveness of different staging strategies for NO x reduction in ammonia combustion. Experimental analysis is undertaken to ascertain the flame stabilization, flame temperature and its reaction zone, intermediate species and major emissions like NO x and NH 3 of the burner. Staging configuration strongly influenced flame stabilization, heat release distribution, and thermal field, with downstream-shifted combustion zones lowering peak temperatures and NO x formation. Among the tested strategies, fuel staging and sequential premixing consistently achieved the greatest NO x reduction across the entire operating range compared to the premixed baseline, without compromising flame stability. Chemical kinetics analysis further reveals the dominant NO formation pathways, highlighting the key roles of HNO and NH i radicals. Additionally, this analysis helps identify dominant reaction routes and the role of intermediate species in NO formation and reduction processes. The combined experimental and kinetic insights provide a mechanistic basis for optimizing staged combustion of ammonia-hydrocarbon blends for lower NO x emissions.

Source: Combustion and Flame

DOI: 10.1016/j.combustflame.2025.114607