Year: 2025
Type: article
Abstract: Possessing two ethylene units, guest triphenylamine derivatives are encapsulated by the cucurbit[8]uril (CB[8]) cavity to induce molecule folding to form a biaxial pseudorotaxane. Crucially, this structure facilitates the oriented polymerization of ethylene units exposed outside the cavity with acrylamide, producing a pure organic supramolecular polymer (p-TAPCB) that exhibits near-infrared (NIR) room-temperature phosphorescence (RTP) with a high quantum yield of 47.03% through the synergistic effect of macrocyclic confinement and polymerization. By adjusting the ratio of CB[8], the resulting copolymers show tunable phosphorescence color that changes depending on the excitation wavelength and concentration. Furthermore, phosphorescence resonance energy transfer (PRET) is employed in triphenylenylborate (TPE) donor-doped polymeric films to flexibly manipulate the NIR emission lifetime from 9.87 ms up to 1490 ms with a large Stokes shift (390 nm). With the advantages of variable emission color and on-demand lifetime, these materials have potential applications in dynamic information encryption.
Source: Chemical Science
DOI: 10.1039/d5sc08027d
Institution: Nankai University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: diamond
Award: G7127553714
OpenAlex ID: W4416569317