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First water-to-ligand substitution dictates Co 2+ /Ni 2+ extraction selectivity

Year: 2026

Type: article

Abstract: First water-to-ligand substitution step exhibits highest free energy gap and controls solvent extraction selectivity.

Source: Physical Chemistry Chemical Physics

DOI: 10.1039/d6cp00202a

Authors: Kailong Zhang, Yuxuan Zhang, Bin Ji, Rick Honaker, Isabel C. Escobar, Jian Shi, Qing Shao

Institution: University of Kentucky

Language: English

Topic: Extraction and Separation Processes

Subfield: Metals and Alloys

Field: Materials Science

Domain: Physical Sciences

SDG: Clean water and sanitation

Open Access status: hybrid

Funders: National Science Foundation, U.S. Department of Energy, National Centre for Supercomputing Applications, Office of Science, Office of Advanced Cyberinfrastructure

Awards: G1453181110, Track 4: Advanced CI Coordination Ecosystem: Monitoring and Measurement Services, CARBON-NEGATIVE CRITICAL METAL RECOVERY FROM E-WASTES THROUGH RESPONSIBLE DESIGN OF SOLVENTS, G3562386289, G3927959030, G3993056153, Track 1: ACCESS Resource Allocations Marketplace and Platform Services (RAMPS), G4010157413, ACO: An Open CI Ecosystem to Advance Scientific Discovery (OpenCI), Track 3: COre National Ecosystem for CyberinfrasTructure (CONECT), G5098925467, G5205022555, G5367127336, G5464919783, G6247045938, G754761654, Track 2: Customized Multi-tier Assistance, Training, and Computational Help (MATCH) for End User ACCESS to CI

OpenAlex ID: W7163199361

FWCI: 1.47

Cites:

Cited by: 1

Related to: 10