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Switching on photoreactivity in Ti 4 -oxo clusters by increasing the size of 1, n -alkane diolate bridging ligands

Year: 2025

Type: article

Abstract: -alkane diolate ligand backbone. Interestingly, the productive photoredox pathway of the 1,5-pentane diolate cluster is turned off when the flexibility of the cluster is restricted in the single crystal phase.

Source: Chemical Science

DOI: 10.1039/d5sc08522e

Authors: Ashwani Chikara, Alexander R. Veale, Stephen E. Brown, Jack M. Woolley, Frank De Proft, Sebastian D. Pike

Institutions: Vrije Universiteit Brussel, University of Warwick

Language: English

Topic: Polyoxometalates: Synthesis and Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: Diamond Light Source, Vlaams Supercomputer Centrum, University of Warwick, Fonds Wetenschappelijk Onderzoek, Vrije Universiteit Brussel, Vlaamse regering, Engineering and Physical Sciences Research Council

Award: G489151498

OpenAlex ID: W4416734658

FWCI: 0.424

Cites: 47

Cited by: 2

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