Work

Preparation Process and Performance of Mineral Admixtures Derived from High-Sulfur Lead-Zinc Tailings

Year: 2025

Type: article

Abstract: The large-scale accumulation of high-sulfur lead–zinc tailings poses serious environmental and safety challenges, while the increasing shortage of traditional mineral admixtures such as fly ash and slag highlights the urgent need for sustainable alternatives. This study aims to develop a high-performance mineral admixture using lead–zinc tailings characterized by high SO3 content and low pozzolanic activity. The effects of four activation routes—mechanical grinding, wet magnetic separation, wet magnetic separation–mechanical grinding, and mechanical grinding–high-reactivity mineral admixture synergistic modification—were systematically compared in terms of tailings fineness, SO3 reduction, and activity index. The results indicate that single mechanical grinding can achieve the fineness requirement of Grade II admixtures specified in GB/T 1596–2017 (45 μm residue ≤ 30%), but the 28-day strength activity index only reached 58.64%, and the SO3 content remained above the standard limit. Wet magnetic separation effectively reduced the SO3 content to below 3.5%, and the combined process yielded a product with an activity index of up to 74.51%. Further improvement was achieved through a “mechanical grinding–high-reactivity mineral admixture synergistic modification” process, incorporating fly ash (FA), ground granulated blast furnace slag (GGBS), and silica fume (SF). Among these, SF exhibited the most pronounced synergistic effect. The optimal mixture, composed of 85.19% ground tailings and 14.81% SF, achieved the highest 28-day activity index of 76.35%. This process enables full utilization of tailings while maintaining a simplified flow, lower energy consumption, and superior product performance. The findings provide a feasible and efficient technological route for the high-value utilization of high-sulfur tailings and contribute to promoting green mining and sustainable resource development.

Source: Minerals

DOI: 10.3390/min15121256