Work

Excess 40Ar retention in metamorphosed amphibole complicates 40Ar/39Ar geochronological interpretation of diabase

Year: 2025

Type: article

Abstract: The 40 Ar/ 39 Ar dating method holds particular significance for determining the age of basic rocks. However, the presence of extraneous argon ( 40 Ar E ) in some samples generates complex 40 Ar/ 39 Ar age spectra, compromising the technique’s utility in modern geochronology. This investigation focuses on deciphering the occurrence of 40 Ar E within a diabase and proposes strategies to mitigate its influence. Our results reveal distinct age patterns: separated feldspar yields a well-defined plateau age of 48.73 ± 0.07 (0.12) [2.06] Ma (2σ, MSWD = 0.86, P = 62%), while whole-rock analyses produce saddle-shaped age spectra. Through integration of EPMA major element data, K/Ca ratios from 40 Ar/ 39 Ar results, and TIMA-derived mineral proportions, we identify metamorphosed amphibole as the primary host of 40 Ar E in this study. Thus, separated components containing metamorphosed amphiboles should be excluded as suitable targets for 40 Ar/ 39 Ar geochronology. These findings provide critical guidance for sample selection and interpretation in basic rocks.

Source: Scientific Reports

DOI: 10.1038/s41598-025-26406-1