Work

Self-assembly of lanthanide-based single-ion magnets (SIMs) into 1D networks via Re( iv )-based metalloligands

Year: 2025

Type: article

Abstract: (4)-exhibit slow relaxation of the magnetisation, which is characteristic of SIM behaviour and accounted for ac magnetic susceptibility measurements. Structural analyses suggest that intra- and intermolecular halogen-halogen (Br⋯Br) interactions may influence the magneto-structural properties of 2-6. These findings demonstrate the potential of Re(IV)-Ln(III) hybrid systems as candidates for developing magnetically addressable molecular materials.

Source: Dalton Transactions

DOI: 10.1039/d5dt01890k

Authors: Carolina Ferrari-Argachá, Santiago Valiero, Carlos Rojas-Dotti, Aparicio Loaces, Raúl Chiozzone, Nicolás Moliner, Leopoldo Suescun, Joan Cano, Francesc Lloret, José Martínez-Lillo, Ricardo González

Institutions: Universidad de la República de Uruguay, Universitat de València

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: hybrid

Funders: Agencia Nacional de Investigación e Innovación, Ministerio de Economía y Competitividad, Generalitat Valenciana, Universidad de la República Uruguay, Comisión Sectorial de Investigación Científica

Awards: G1368042953, G3042866102, G4902752058, G6755560743, G797086492

OpenAlex ID: W4416900429

FWCI: 0.326

Cites: 51

Cited by: 2

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