Work

Modification of Polypropylene Fibers with Sodium Silicate: Enhancement of Pozzolanic Properties in Cement-Based Systems

Year: 2025

Type: article

Abstract: This study investigates the effect of sodium-silicate-based chemical surface modification of polypropylene (PP) fibers on the mechanical and fresh-state properties of cementitious composites. The proposed method introduces silanol and siloxane groups onto the PP surface through a radical-assisted chlorination route, aiming to enhance fiber-matrix interfacial bonding. Modified fibers increased the polycarboxylate ether (PCE) demand by 100% compared to the control mixture, while unmodified PP fibers caused a 58% increase at equivalent workability. The incorporation of PP fibers resulted in limited changes in compressive strength (1-7%), whereas silicate-modified fibers led to notable late-age flexural strength gains of 10% (28 days) and 17% (56 days). Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDX) and Fourier Transform Infrared Spectroscopy (FTIR) analyses confirmed successful surface functionalization, while the heterogeneous silicate deposition still contributed positively to interfacial transition zone (ITZ) performance. Overall, sodium-silicate-modified PP fibers improve flexural behavior and interfacial bonding in cement-based systems, offering a promising approach for enhanced mechanical performance and sustainability.

Source: Polymers

DOI: 10.3390/polym17233206

Authors: Yahya Kaya, Petek Balcı, Süleyman Özen, Ali Mardani, Ali Kara

Institutions: Bursa Uludağ Üni̇versi̇tesi̇, Bursa Technical University

Language: English

Topic: Innovative concrete reinforcement materials

Subfield: Civil and Structural Engineering

Field: Engineering

Domain: Physical Sciences

SDG: Industry, innovation and infrastructure

Open Access status: gold

Estimated APC paid: $3,258